Analysis by kinetic modeling of the temperature dependence of thermal electron attachment to CF3Br.

Electron attachment to CF3 and CF3Br at temperatures up to 890 K: experimental test of the kinetic modeling approach.

Thermal rate constants and product branching fractions for electron attachment to CF3Br and the CF3 radical have been measured over the temperature range 300-890 K, the upper limit being restricted by thermal decomposition of CF3Br. Both measurements were made in Flowing Afterglow Langmuir Probe apparatuses; the CF3Br measurement was made using standard techniques, and the CF3 measurement using...

Electron attachment to C2 fluorocarbon radicals at high temperature.

Thermal electron attachment to the radical species C2F3 and C2F5 has been studied over the temperature range 300-890 K using the Variable Electron and Neutral Density Attachment Mass Spectrometry technique. Both radicals exclusively undergo dissociative attachment to yield F(-). The rate constant for C2F5 shows little dependence over the temperature range, remaining ~4 × 10(-9) cm(3) s(-1). The...

Pressure and temperature dependence of dissociative and non-dissociative electron attachment to CF3: experiments and kinetic modeling.

The kinetics of electron attachment to CF(3) as a function of temperature (300-600 K) and pressure (0.75-2.5 Torr) were studied by variable electron and neutral density attachment mass spectrometry exploiting dissociative electron attachment to CF(3)Br as a radical source. Attachment occurs through competing dissociative (CF(3) + e(-) → CF(2) + F(-)) and non-dissociative channels (CF(3) + e(-) ...

Pressure and Temperature Dependence of Dissociative and Non-dissociative Electron Attachment to Cf3: Experiments and Kinetic Modeling (postprint)

KINETIC STUDY OF TRR CORE IN FUEL CONVERSION FROM HEU TO LEU

In the conversion of fuel in the Tehran Research Reactor core from Highly- Enriched Uraniutn to Low-Enriched Uranium fuel neutronics analysis, thermal hydraulic calculations and kinetic performance of the core have to be studied. In this study, static and dynamic core performance for HEU and LEU fuels were investigated. In static conditions, two groups of neutron flux distributions in axia...